Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969558985> ?p ?o ?g. }
- W1969558985 abstract "Abstract Mono-nuclear complexes [M(CPI)6](X)2 (M = Co, X = NO3− 1; M = Ni, X = NO3− 2; M = Cu, X = ClO4− 3) and [Cu(CPI)4(H2O)2](NO3)2 4, based on novel bridging ligand 1-(4-cyanophenyl)-imidazole (CPI) are reported. The complexes have been characterized by elemental analyses, spectral studies and their molecular structures have been authenticated by single crystal X-ray diffraction analyses. In molecular species 1–3 metal centers are coordinated octahedrally by six CPI ligands wherein cyanophenyl rings of six ligands about the complex cations are involved in face-to-face π–π interaction with six co-planar molecules to afford unprecedented 2D sheet. Along ‘c’-axis it gives a beautiful rim like motif. In complex 4, coordination about metal center Cu is distorted octahedral with four CPI ligands in the equatorial position and two water molecules occupying axial positions. In this complex hydrogen bonding interactions between the coordinated water molecules and nitrate anions results in a 1D straight chain along ‘a’-axis and 2D sheets having hexagonal cavity filled by nitrate ions. The complexes upon excitation at 275–285 nm exhibit luminescences with emission maxima centered at 438–445 nm attributable to the ligand CPI at room temperature." @default.
- W1969558985 created "2016-06-24" @default.
- W1969558985 creator A5034434638 @default.
- W1969558985 creator A5048943460 @default.
- W1969558985 creator A5051096265 @default.
- W1969558985 creator A5079224398 @default.
- W1969558985 creator A5083797035 @default.
- W1969558985 creator A5085601592 @default.
- W1969558985 date "2009-10-01" @default.
- W1969558985 modified "2023-09-25" @default.
- W1969558985 title "Novel structures based on 1-(4-cyanophenyl)-imidazole resulting from weak bonding interactions" @default.
- W1969558985 cites W1639617622 @default.
- W1969558985 cites W1677747913 @default.
- W1969558985 cites W1822092150 @default.
- W1969558985 cites W1897085524 @default.
- W1969558985 cites W1969702989 @default.
- W1969558985 cites W1975501285 @default.
- W1969558985 cites W1987556773 @default.
- W1969558985 cites W1987928326 @default.
- W1969558985 cites W1988475203 @default.
- W1969558985 cites W1989439140 @default.
- W1969558985 cites W1992028426 @default.
- W1969558985 cites W1993210268 @default.
- W1969558985 cites W1997523713 @default.
- W1969558985 cites W1998204948 @default.
- W1969558985 cites W2007068681 @default.
- W1969558985 cites W2014054292 @default.
- W1969558985 cites W2014389422 @default.
- W1969558985 cites W2014965018 @default.
- W1969558985 cites W2015700500 @default.
- W1969558985 cites W2019569461 @default.
- W1969558985 cites W2020136467 @default.
- W1969558985 cites W2026654671 @default.
- W1969558985 cites W2028451357 @default.
- W1969558985 cites W2029165172 @default.
- W1969558985 cites W2029742396 @default.
- W1969558985 cites W2032008602 @default.
- W1969558985 cites W2044422763 @default.
- W1969558985 cites W2054468570 @default.
- W1969558985 cites W2059599439 @default.
- W1969558985 cites W2072010051 @default.
- W1969558985 cites W2075132854 @default.
- W1969558985 cites W2076070702 @default.
- W1969558985 cites W2077875870 @default.
- W1969558985 cites W2078444809 @default.
- W1969558985 cites W2080033165 @default.
- W1969558985 cites W2082274183 @default.
- W1969558985 cites W2086659534 @default.
- W1969558985 cites W2089334254 @default.
- W1969558985 cites W2103680519 @default.
- W1969558985 cites W2105218596 @default.
- W1969558985 cites W2120433419 @default.
- W1969558985 cites W2157107902 @default.
- W1969558985 cites W50657859 @default.
- W1969558985 doi "https://doi.org/10.1016/j.molstruc.2009.06.031" @default.
- W1969558985 hasPublicationYear "2009" @default.
- W1969558985 type Work @default.
- W1969558985 sameAs 1969558985 @default.
- W1969558985 citedByCount "4" @default.
- W1969558985 countsByYear W19695589852019 @default.
- W1969558985 crossrefType "journal-article" @default.
- W1969558985 hasAuthorship W1969558985A5034434638 @default.
- W1969558985 hasAuthorship W1969558985A5048943460 @default.
- W1969558985 hasAuthorship W1969558985A5051096265 @default.
- W1969558985 hasAuthorship W1969558985A5079224398 @default.
- W1969558985 hasAuthorship W1969558985A5083797035 @default.
- W1969558985 hasAuthorship W1969558985A5085601592 @default.
- W1969558985 hasConcept C112887158 @default.
- W1969558985 hasConcept C115624301 @default.
- W1969558985 hasConcept C116569031 @default.
- W1969558985 hasConcept C145148216 @default.
- W1969558985 hasConcept C170493617 @default.
- W1969558985 hasConcept C178790620 @default.
- W1969558985 hasConcept C185592680 @default.
- W1969558985 hasConcept C198819137 @default.
- W1969558985 hasConcept C2780874372 @default.
- W1969558985 hasConcept C32909587 @default.
- W1969558985 hasConcept C544153396 @default.
- W1969558985 hasConcept C55493867 @default.
- W1969558985 hasConcept C71240020 @default.
- W1969558985 hasConcept C8010536 @default.
- W1969558985 hasConceptScore W1969558985C112887158 @default.
- W1969558985 hasConceptScore W1969558985C115624301 @default.
- W1969558985 hasConceptScore W1969558985C116569031 @default.
- W1969558985 hasConceptScore W1969558985C145148216 @default.
- W1969558985 hasConceptScore W1969558985C170493617 @default.
- W1969558985 hasConceptScore W1969558985C178790620 @default.
- W1969558985 hasConceptScore W1969558985C185592680 @default.
- W1969558985 hasConceptScore W1969558985C198819137 @default.
- W1969558985 hasConceptScore W1969558985C2780874372 @default.
- W1969558985 hasConceptScore W1969558985C32909587 @default.
- W1969558985 hasConceptScore W1969558985C544153396 @default.
- W1969558985 hasConceptScore W1969558985C55493867 @default.
- W1969558985 hasConceptScore W1969558985C71240020 @default.
- W1969558985 hasConceptScore W1969558985C8010536 @default.
- W1969558985 hasLocation W19695589851 @default.
- W1969558985 hasOpenAccess W1969558985 @default.
- W1969558985 hasPrimaryLocation W19695589851 @default.
- W1969558985 hasRelatedWork W1967915170 @default.
- W1969558985 hasRelatedWork W1971280024 @default.