Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969578712> ?p ?o ?g. }
- W1969578712 endingPage "9654" @default.
- W1969578712 startingPage "9648" @default.
- W1969578712 abstract "The electron self-exchange rate constants of blue copper model complexes, [(−)-sparteine-N,N‘](maleonitriledithiolato-S,S‘)copper ([Cu(SP)(mmt)])0/-, bis(2,9-dimethy-1,10-phenanthroline)copper ([Cu(dmp)2]2+/+), and bis(1,10-phenanthroline)copper ([Cu(phen)2]2+/+) have been determined from the rate constants of electron transfer from a homologous series of ferrocene derivatives to the copper(II) complexes in light of the Marcus theory of electron transfer. The resulting electron self-exchange rate constant increases in the order: [Cu(phen)2]2+/+ < [Cu(SP)(mmt)]0/- < [Cu(dmp)2]2+/+, in agreement with the order of the smaller structural change between the copper(II) and copper(I) complexes due to the distorted tetragonal geometry. The dye-sensitized solar cells (DSSC) were constructed using the copper complexes as redox couples to compare the photoelectrochemical responses with those using the conventional I3-/I- couple. The light energy conversion efficiency (η) values under illumination of simulated solar light irradiation (100 mW/cm2) of DSSCs using [Cu(phen)2]2+/+, [Cu(dmp)2]2+/+, and [Cu(SP)(mmt)]0/- were recorded as 0.1%, 1.4%, and 1.3%, respectively. The maximum η value (2.2%) was obtained for a DSSC using the [Cu(dmp)2]2+/+ redox couple under the light irradiation of 20 mW/cm2 intensity, where a higher open-circuit voltage of the cell was attained as compared to that of the conventional I3-/I- couple." @default.
- W1969578712 created "2016-06-24" @default.
- W1969578712 creator A5008430075 @default.
- W1969578712 creator A5016648385 @default.
- W1969578712 creator A5036971951 @default.
- W1969578712 creator A5066193981 @default.
- W1969578712 date "2005-06-10" @default.
- W1969578712 modified "2023-10-03" @default.
- W1969578712 title "Blue Copper Model Complexes with Distorted Tetragonal Geometry Acting as Effective Electron-Transfer Mediators in Dye-Sensitized Solar Cells" @default.
- W1969578712 cites W1540571608 @default.
- W1969578712 cites W1965518970 @default.
- W1969578712 cites W1971415655 @default.
- W1969578712 cites W1972739804 @default.
- W1969578712 cites W1975688292 @default.
- W1969578712 cites W1976248955 @default.
- W1969578712 cites W1976980537 @default.
- W1969578712 cites W1980216394 @default.
- W1969578712 cites W1984576643 @default.
- W1969578712 cites W1985807365 @default.
- W1969578712 cites W1994989810 @default.
- W1969578712 cites W2002899540 @default.
- W1969578712 cites W2006051756 @default.
- W1969578712 cites W2007814348 @default.
- W1969578712 cites W2011740529 @default.
- W1969578712 cites W2016138958 @default.
- W1969578712 cites W2016616196 @default.
- W1969578712 cites W2018926708 @default.
- W1969578712 cites W2020629753 @default.
- W1969578712 cites W2023793218 @default.
- W1969578712 cites W2024140372 @default.
- W1969578712 cites W2027140236 @default.
- W1969578712 cites W2031904472 @default.
- W1969578712 cites W2034561754 @default.
- W1969578712 cites W2034600111 @default.
- W1969578712 cites W2037509078 @default.
- W1969578712 cites W2046250558 @default.
- W1969578712 cites W2047364735 @default.
- W1969578712 cites W2048247575 @default.
- W1969578712 cites W2048293309 @default.
- W1969578712 cites W2048645097 @default.
- W1969578712 cites W2055069556 @default.
- W1969578712 cites W2055267039 @default.
- W1969578712 cites W2056396660 @default.
- W1969578712 cites W2059756314 @default.
- W1969578712 cites W2067623205 @default.
- W1969578712 cites W2075247879 @default.
- W1969578712 cites W2078439938 @default.
- W1969578712 cites W2082442378 @default.
- W1969578712 cites W2083995766 @default.
- W1969578712 cites W2086687059 @default.
- W1969578712 cites W2089488664 @default.
- W1969578712 cites W2089935707 @default.
- W1969578712 cites W2091237955 @default.
- W1969578712 cites W2093239268 @default.
- W1969578712 cites W2093643972 @default.
- W1969578712 cites W2096474770 @default.
- W1969578712 cites W2099954427 @default.
- W1969578712 cites W2160503129 @default.
- W1969578712 cites W2163298313 @default.
- W1969578712 cites W2235602270 @default.
- W1969578712 cites W2441847090 @default.
- W1969578712 cites W2604531286 @default.
- W1969578712 cites W2952953177 @default.
- W1969578712 cites W3011459335 @default.
- W1969578712 cites W3135964318 @default.
- W1969578712 cites W3136472852 @default.
- W1969578712 cites W4211022679 @default.
- W1969578712 cites W4213245659 @default.
- W1969578712 cites W4236537097 @default.
- W1969578712 cites W4241456496 @default.
- W1969578712 doi "https://doi.org/10.1021/ja0506814" @default.
- W1969578712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15984893" @default.
- W1969578712 hasPublicationYear "2005" @default.
- W1969578712 type Work @default.
- W1969578712 sameAs 1969578712 @default.
- W1969578712 citedByCount "280" @default.
- W1969578712 countsByYear W19695787122012 @default.
- W1969578712 countsByYear W19695787122013 @default.
- W1969578712 countsByYear W19695787122014 @default.
- W1969578712 countsByYear W19695787122015 @default.
- W1969578712 countsByYear W19695787122016 @default.
- W1969578712 countsByYear W19695787122017 @default.
- W1969578712 countsByYear W19695787122018 @default.
- W1969578712 countsByYear W19695787122019 @default.
- W1969578712 countsByYear W19695787122020 @default.
- W1969578712 countsByYear W19695787122021 @default.
- W1969578712 countsByYear W19695787122022 @default.
- W1969578712 countsByYear W19695787122023 @default.
- W1969578712 crossrefType "journal-article" @default.
- W1969578712 hasAuthorship W1969578712A5008430075 @default.
- W1969578712 hasAuthorship W1969578712A5016648385 @default.
- W1969578712 hasAuthorship W1969578712A5036971951 @default.
- W1969578712 hasAuthorship W1969578712A5066193981 @default.
- W1969578712 hasConcept C113196181 @default.
- W1969578712 hasConcept C115624301 @default.
- W1969578712 hasConcept C121332964 @default.
- W1969578712 hasConcept C123669783 @default.
- W1969578712 hasConcept C147789679 @default.