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- W1969587834 abstract "The diffusion of ferrocene methanol in super-cooled aqueous solutions containing sucrose has been studied, using disk and cylindrical microelectrodes, over a wide viscosity range. The solution viscosity and the reduced temperature T/Tg (Tg being the glass transition temperature) were varied by changing the sucrose concentration and the temperature of the system. The voltammetric limiting current obtained with a disk microelectrode and the i(t) response on a cylindrical microelectrode after a potential step were used to determine diffusion coefficients from 7 × 10−6 cm2 s−1 down to 2 × 10−11 cm2 s−1. The electrochemical procedure described in this work allows a simple and accurate measurement of the dynamics of electroactive solutes in glass-forming liquids." @default.
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- W1969587834 date "1989-08-01" @default.
- W1969587834 modified "2023-10-18" @default.
- W1969587834 title "Cryo-electrochemistry: new observations" @default.
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- W1969587834 doi "https://doi.org/10.1016/0022-0728(89)80265-7" @default.
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