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- W1969603226 abstract "Abstract Reactions of CF 3 CF 2 CFCCl 2 ( 1 ) with various nucleophiles such as MeO − , PhO − , NH 3 , n-c 4 H 9 MgBr and n-C 4 H 9 S − were studied. Contrary to a prior report [3], the addition is bidirectional and except for Pho − , nucleophiles would rather attack the CF site (path 1) than the CCL 2 site (path 2), no matter whether the base is soft or hard. PhO − attacked both sites at nearly 1:1 ratio. Temperature had little effect on the direction of Meo − attack, but solvents could change its reaction rate and the distribution of products. Compared with CF 2 CFCF 2 CFCFCl 2 ( 2 ) and CF 3 CFCFCFCl 2 (trans, 3 ), preliminary experiments indicated that the order of reactivity increases along with the series of 1 ." @default.
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- W1969603226 date "1989-01-01" @default.
- W1969603226 modified "2023-09-23" @default.
- W1969603226 title "Reactions of perchlorofluoro compounds IV. The reaction of 1,1-dichlorohexafluoro-1-butene with some nucleophiles" @default.
- W1969603226 cites W2329037939 @default.
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- W1969603226 doi "https://doi.org/10.1016/s0022-1139(00)83968-8" @default.
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