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- W1969609512 abstract "Systematic studies on free-radical additions of acyclic ethers to hexafluoropropene reveal the influence of steric effects on the competitive formation of mono-, di-, and tri-adducts. It is concluded that ‘capto-dative’ effects are not dominant in systems containing polyfluoroalkyl groups. Remarkably efficient free-radical additions of trialkyl borates, to fluorinated alkenes occur, but in a series X-OMe (X = MeCO, HCO, MeOCO etc.) reactivity is reduced by electron withdrawal." @default.
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- W1969609512 date "1985-01-01" @default.
- W1969609512 modified "2023-09-27" @default.
- W1969609512 title "Free radical chemistry. Part 3. Substituent effects in additions of ethers to fluorinated alkenes" @default.
- W1969609512 doi "https://doi.org/10.1039/p19850002209" @default.
- W1969609512 hasPublicationYear "1985" @default.
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