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- W1969629811 abstract "The surface structure and properties of synthetic colloidal calcium hydroxyapatite, Ca10(PO4)6(OH)2 (abbreviated as CaHap), were investigated. The CaHap surface possesses three kinds of P-OH groups acting as adsorption sites for H2O, CO2, CH3I, CH3OH and so on. The number of surface P-OH groups was ca. 2.6 groups nm−2. When the CaHap was outgassed above 400oC, the surface P-OH groups were dehydroxylated to form surface P-O-P groups. Based on the results obtained, the surface design of CaHap by modifying it with various inorganic and organic molecules was made. The hydrophilic CaHap surface turned into a hydrophobic surface by modification with monoalkyl phosphates and hexamethyldisilazane. The surface P-O-Si(CH3)3 groups of CaHap modified with hexamethyldisilazane were combusted at 500oC in air to form surface P-O-Si(OH)3 groups. The number and types of surface P-OH groups of the CaHap could be controlled by treating with pyrophosphoric acid." @default.
- W1969629811 created "2016-06-24" @default.
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- W1969629811 date "2003-01-01" @default.
- W1969629811 modified "2023-09-24" @default.
- W1969629811 title "Surface Characterization and Design of Synthetic Calcium Hydroxyapatite" @default.
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- W1969629811 doi "https://doi.org/10.1380/jsssj.24.620" @default.
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