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• W1969642702 abstract "The electrophoretic behavior of concentrated spherical colloidal particles is analyzed theoretically for all levels of scaled surface potential φa, taking the effect of double-layer polarization (DLP) into account. The result of numerical simulation reveals that for a very small κa(<0.01), κ andabeing, respectively, the reciprocal Debye length and the particle radius, or a very large κa(>100), using a linearized Poisson–Boltzmann equation (PBE) and neglecting the effect of DLP is reasonable; for an intermediate κa, appreciable deviation may result. The deviation is negative if κais small, and positive if κais large. The mobility against κacurve may have a local minimum and a local maximum. If φais low, the mobility increases with the porosity of the system under consideration, and for a fixed porosity, the mobility increases with κa. If φais high and κais small, the effect of φa(i.e., solving a nonlinear PBE) on the mobility of a particle is more significant than that of double-layer polarization, and the reverse is true if κais large. For an intermediate κa, the effect of DLP is more significant than that of φawhen the porosity is high, and the reverse is true if it is low." @default.
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• W1969642702 date "1999-01-01" @default.
• W1969642702 modified "2023-10-14" @default.
• W1969642702 title "Electrophoretic Mobility of a Concentrated Suspension of Spherical Particles" @default.
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• W1969642702 doi "https://doi.org/10.1006/jcis.1998.5886" @default.
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