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- W1969646637 abstract "Abstract An efficient convergent route to the main chain type of organometallic dendrimers, in which platinum moieties are linked by 1,3,5‐triethynylbenzene, has been developed. The synthesis of platinum–acetylide dendrons involved the use of two types of trialkylsilyl groups for protection of the terminal acetylene. The platinum–acetylide dendrimers were prepared up to the third generation by reacting dendrons with a triplatinum core and a tetraplatinum core. Spectroscopic characterization and trace experiments by gel permeation chromatography indicated that the dendrimer molecules have no structural defects. Although a π‐conjugated system was used as the bridging ligand, electronic and fluorescence spectra suggested that the interaction among the platinum–acetylide moieties in the dendrimers was small." @default.
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- W1969646637 date "2004-12-01" @default.
- W1969646637 modified "2023-10-12" @default.
- W1969646637 title "Convergent Synthesis of Platinum-Acetylide Dendrimers" @default.
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- W1969646637 doi "https://doi.org/10.1002/chem.200400544" @default.
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