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• W1969654398 abstract "The conformational behaviour of trimethyl phosphate was studied by infrared spectroscopy in the liquid phase and as 1% solutions in a wide range of solvents. Variable temperature studies carried out in carbon disulphide and liquid xenon solutions, and in the pure liquid phase, showed a reversal in the relative stability of the two conformers between liquid xenon and carbon disulphide solutions. In liquid xenon solution the less polar conformer II is ≈ 1.8 kJ mol−1 lower in energy, whereas in CS2 solution the more polar conformer I is ≈ 1.4 kJ mol−1 more stable. In the pure liquid, the energy difference between the two conformers is similar to that in carbon disulphide solution. Ab initio calculations predict that conformer II has C3 symmetry with all the methoxy groups in the gauche configuration, whereas conformer I has C1 symmetry with one trans and two gauche methoxy groups." @default.
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• W1969654398 date "1996-02-01" @default.
• W1969654398 modified "2023-09-27" @default.
• W1969654398 title "Conformational behaviour of trimethyl phosphate studied by infrared spectroscopy" @default.
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• W1969654398 doi "https://doi.org/10.1016/0022-2860(95)09106-8" @default.
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