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• W1969679149 abstract "Triarylborane Lewis acids bind [Fe2(pdt)(CO)4(CN)2]2– [1]2– (pdt2– = 1,3-propanedithiolate) and [Fe2(adt)(CO)4(CN)2]2– [3]2– (adt2– = 1,3-azadithiolate, HN(CH2S–)2) to give the 2:1 adducts [Fe2(xdt)(CO)4(CNBAr3)2]2–. Attempts to prepare the 1:1 adducts [1(BAr3)]2– (Ar = Ph, C6F5) were unsuccessful, but related 1:1 adducts were obtained using the bulky borane B(C6F4-o-C6F5)3 (BArF*3). By virtue of the N-protection by the borane, salts of [Fe2(pdt)(CO)4(CNBAr3)2]2– sustain protonation to give hydrides that are stable (in contrast to [H1]−). The hydrides [H1(BAr3)2]− are 2.5–5 pKa units more acidic than the parent [H1]−. The adducts [1(BAr3)2]2– oxidize quasi-reversibly around −0.3 V versus Fc0/+ in contrast to ca. −0.8 V observed for the [1]2–/– couple. A simplified synthesis of [1]2–, [3]2–, and [Fe2(pdt)(CO)5(CN)]− ([2]−) was developed, entailing reaction of the diiron hexacarbonyl complexes with KCN in MeCN." @default.
• W1969679149 created "2016-06-24" @default.
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• W1969679149 date "2014-07-03" @default.
• W1969679149 modified "2023-09-25" @default.
• W1969679149 title "Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models" @default.
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• W1969679149 doi "https://doi.org/10.1021/ic500470z" @default.
• W1969679149 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4364604" @default.
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