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• W1969688600 abstract "According to most of works in the literature, adsorbed carbon monoxide at Pt(1 1 0) electrodes in acid media presents only linear bonded (COL) so-called, atop geometry. In the present work, the formation of bridge bonded carbon monoxide (COB) is shown via in situ infrared FT spectra, measured on a Pt(1 1 0) electrode covered with 25% CO, in HClO4 solutions. For the first time, the inter conversion between atop and bridge bonded CO at potentials in the hydrogen adsorption region is reported in acid solution. Band intensity and band center frequency indicate dipole–dipole coupling effects in spite of the low CO total coverage." @default.
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• W1969688600 date "2002-12-01" @default.
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• W1969688600 title "A spectroscopic proof of a surface equilibrium between on top and bridge bonded CO at Pt(110) in acid solution" @default.
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• W1969688600 doi "https://doi.org/10.1016/s1388-2481(02)00497-6" @default.
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