FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969694057> ?p ?o ?g. }

• W1969694057 endingPage "11978" @default.
• W1969694057 startingPage "11973" @default.
• W1969694057 abstract "Optical absorption of single-crystal, cerium-doped lutetium oxyorthosilicate has been carefully measured in the temperature interval 10--300 K. Prominent Gaussian absorption peaks occur at $3.432ifmmodepmelsetextpmfi{}0.002mathrm{eV}$ (peak a), $3.502ifmmodepmelsetextpmfi{}0.002mathrm{eV}$ (peak b), $4.236ifmmodepmelsetextpmfi{}0.0002mathrm{eV}$ (peak c), and $4.746ifmmodepmelsetextpmfi{}0.0002mathrm{eV}$ (peak d), in excellent agreement with previously reported excitation spectra. The second moments are well described by the usual linear model, yielding the Huang-Rhys parameter (S) and vibrational quantum energies for the individual peaks. All absorption bands are characterized by $S>5$ indicating strong coupling between the ${mathrm{Ce}}^{3+}$ ion and lattice. Temperature dependence of the band centroids exhibits contrasting behavior that is dominated by higher-order coupling terms in the linear harmonic oscillator model or by crystal-field effects. Oscillator strengths of the $4stackrel{ensuremath{rightarrow}}{f}5d$ transitions are calculated from Smakula's formula and knowledge of the ${mathrm{Ce}}^{3+}$ distribution between the two crystallographically inequivalent sites. Values for peaks b, c, and d range from approximately 0.003 to 0.004, and peak a spans magnitude approximately 0.012 to 0.018. From the known correlation between average ${mathrm{Ce}}^{3+}$-ion-ligand distance and oscillator strength, we tentatively conclude that peak a is correlated with the seven-oxygen-coordinated site, and peaks b, c, and d are associated with the six-oxygen-coordinated site. These results support the previously proposed two-activation-center model and identify the centers as the two crystallographically inequivalent substitutional sites." @default.
• W1969694057 created "2016-06-24" @default.
• W1969694057 creator A5001659696 @default.
• W1969694057 creator A5010263688 @default.
• W1969694057 creator A5025590219 @default.
• W1969694057 creator A5030009294 @default.
• W1969694057 creator A5043654353 @default.
• W1969694057 creator A5082965366 @default.
• W1969694057 date "2000-05-01" @default.
• W1969694057 modified "2023-09-26" @default.
• W1969694057 title "Electron-lattice coupling parameters and oscillator strengths of cerium-doped lutetium oxyorthosilicate" @default.
• W1969694057 cites W1972590233 @default.
• W1969694057 cites W200854152 @default.
• W1969694057 cites W2013433494 @default.
• W1969694057 cites W2016025507 @default.
• W1969694057 cites W2047237913 @default.
• W1969694057 cites W2048936738 @default.
• W1969694057 cites W2054032314 @default.
• W1969694057 cites W2062165112 @default.
• W1969694057 cites W2086270484 @default.
• W1969694057 cites W2091896430 @default.
• W1969694057 cites W2101749072 @default.
• W1969694057 cites W2122169792 @default.
• W1969694057 cites W2123210368 @default.
• W1969694057 cites W2136242954 @default.
• W1969694057 cites W2141647851 @default.
• W1969694057 cites W4232994806 @default.
• W1969694057 doi "https://doi.org/10.1103/physrevb.61.11973" @default.
• W1969694057 hasPublicationYear "2000" @default.
• W1969694057 type Work @default.
• W1969694057 sameAs 1969694057 @default.
• W1969694057 citedByCount "51" @default.
• W1969694057 countsByYear W19696940572012 @default.
• W1969694057 countsByYear W19696940572014 @default.
• W1969694057 countsByYear W19696940572015 @default.
• W1969694057 countsByYear W19696940572016 @default.
• W1969694057 countsByYear W19696940572017 @default.
• W1969694057 countsByYear W19696940572018 @default.
• W1969694057 countsByYear W19696940572019 @default.
• W1969694057 countsByYear W19696940572020 @default.
• W1969694057 countsByYear W19696940572022 @default.
• W1969694057 countsByYear W19696940572023 @default.
• W1969694057 crossrefType "journal-article" @default.
• W1969694057 hasAuthorship W1969694057A5001659696 @default.
• W1969694057 hasAuthorship W1969694057A5010263688 @default.
• W1969694057 hasAuthorship W1969694057A5025590219 @default.
• W1969694057 hasAuthorship W1969694057A5030009294 @default.
• W1969694057 hasAuthorship W1969694057A5043654353 @default.
• W1969694057 hasAuthorship W1969694057A5082965366 @default.
• W1969694057 hasConcept C119824511 @default.
• W1969694057 hasConcept C120665830 @default.
• W1969694057 hasConcept C121332964 @default.
• W1969694057 hasConcept C125287762 @default.
• W1969694057 hasConcept C1276947 @default.
• W1969694057 hasConcept C145148216 @default.
• W1969694057 hasConcept C184779094 @default.
• W1969694057 hasConcept C191897082 @default.
• W1969694057 hasConcept C192562407 @default.
• W1969694057 hasConcept C26873012 @default.
• W1969694057 hasConcept C2779851234 @default.
• W1969694057 hasConcept C4839761 @default.
• W1969694057 hasConcept C520551903 @default.
• W1969694057 hasConcept C523597863 @default.
• W1969694057 hasConcept C531131001 @default.
• W1969694057 hasConcept C57863236 @default.
• W1969694057 hasConcept C62520636 @default.
• W1969694057 hasConcept C99191460 @default.
• W1969694057 hasConceptScore W1969694057C119824511 @default.
• W1969694057 hasConceptScore W1969694057C120665830 @default.
• W1969694057 hasConceptScore W1969694057C121332964 @default.
• W1969694057 hasConceptScore W1969694057C125287762 @default.
• W1969694057 hasConceptScore W1969694057C1276947 @default.
• W1969694057 hasConceptScore W1969694057C145148216 @default.
• W1969694057 hasConceptScore W1969694057C184779094 @default.
• W1969694057 hasConceptScore W1969694057C191897082 @default.
• W1969694057 hasConceptScore W1969694057C192562407 @default.
• W1969694057 hasConceptScore W1969694057C26873012 @default.
• W1969694057 hasConceptScore W1969694057C2779851234 @default.
• W1969694057 hasConceptScore W1969694057C4839761 @default.
• W1969694057 hasConceptScore W1969694057C520551903 @default.
• W1969694057 hasConceptScore W1969694057C523597863 @default.
• W1969694057 hasConceptScore W1969694057C531131001 @default.
• W1969694057 hasConceptScore W1969694057C57863236 @default.
• W1969694057 hasConceptScore W1969694057C62520636 @default.
• W1969694057 hasConceptScore W1969694057C99191460 @default.
• W1969694057 hasIssue "18" @default.
• W1969694057 hasLocation W19696940571 @default.
• W1969694057 hasOpenAccess W1969694057 @default.
• W1969694057 hasPrimaryLocation W19696940571 @default.
• W1969694057 hasRelatedWork W1663927036 @default.
• W1969694057 hasRelatedWork W1994771618 @default.
• W1969694057 hasRelatedWork W2019662253 @default.
• W1969694057 hasRelatedWork W2024361131 @default.
• W1969694057 hasRelatedWork W2063240841 @default.
• W1969694057 hasRelatedWork W2361959771 @default.
• W1969694057 hasRelatedWork W2388316824 @default.
• W1969694057 hasRelatedWork W3105890913 @default.
• W1969694057 hasRelatedWork W4200161497 @default.

• next