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• W1969694547 abstract "A b initio configuration interaction calculations using effective core potentials are presented for the low-lying electronic states of HgCl and HgBr. The B→X laser wavelengths and vibrational constants for the B and X states are in very good agreement with experiment. The equilibrium separations (Re) for the B and X states in HgCl (HgBr) are found to be 2.42 (2.61 Å) and 2.93 Å (3.04 Å), respectively. The purely electronic radiative lifetime for the B state in HgCl (HgBr) is calculated to be 27.5 ns (27.6 ns). The mixing of ionic and covalent character in the X and B states and its effect on the R dependence of the transition moment is discussed briefly. Finally, the possibility of self-absorption is considered." @default.
• W1969694547 created "2016-06-24" @default.
• W1969694547 creator A5082607263 @default.
• W1969694547 date "1979-05-15" @default.
• W1969694547 modified "2023-09-23" @default.
• W1969694547 title "The electronic structure of HgCl and HgBr" @default.
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• W1969694547 doi "https://doi.org/10.1063/1.90627" @default.
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