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- W1969698724 abstract "Studies of the Earth's atmosphere have shown that more than 90% of the expected amount of Xe is depleted, a finding often referred to as the ‘missing Xe paradox’. Although several models for a Xe reservoir have been proposed, whether the missing Xe could be contained in the Earth's inner core has not yet been answered. The key to addressing this issue lies in the reactivity of Xe with Fe/Ni, the main constituents of the Earth's core. Here, we predict, through first-principles calculations and unbiased structure searching techniques, a chemical reaction of Xe with Fe/Ni at the temperatures and pressures found in the Earth's core. We find that, under these conditions, Xe and Fe/Ni can form intermetallic compounds, of which XeFe3 and XeNi3 are energetically the most stable. This shows that the Earth's inner core is a natural reservoir for Xe storage and provides a solution to the missing Xe paradox. Studies of the Earth's atmosphere have shown that more than 90% of xenon is depleted — the so-called missing Xe paradox. Now a theoretical study shows that Xe and Fe/Ni can form inter-metallic compounds of XeFe3 and XeNi3 under conditions found in the Earth's inner core, and could provide a solution to the puzzle." @default.
- W1969698724 created "2016-06-24" @default.
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- W1969698724 date "2014-04-20" @default.
- W1969698724 modified "2023-10-17" @default.
- W1969698724 title "Reactions of xenon with iron and nickel are predicted in the Earth's inner core" @default.
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- W1969698724 doi "https://doi.org/10.1038/nchem.1925" @default.
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