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- W1969719681 abstract "Eleven to twenty membered macrocyclic formals have been synthesized from the corresponding polyethylene glycols and paraformaldehyde. Their activating efficiency has been measured in nucleophilic substitution reactions with alkali metal ions as counter ions. These macrocyclic formals were not as good compiexing agents as crown ethers, but were much better than open chain polyethers which had the same number of oxygen atoms. In the reaction of butyl bromide with alkali metal acetate, 1,3,6,9,12,15-hexaoxacycloheptadecane was several times more effective than pentaethylene glycol dimethyl ether." @default.
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- W1969719681 date "1978-10-01" @default.
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- W1969719681 title "Macrocyclic Formals. IV. Macrocyclic Formals as Compiexing Agents" @default.
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- W1969719681 doi "https://doi.org/10.1246/bcsj.51.3053" @default.
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