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- W1969722214 abstract "The reactivity of a range of electrophilic organic substrates with a heterobimetallic tantalum−lithium bridging alkylidene [(Me3SiCH2)(ArN)Ta(μ-CHSiMe3)(μ-η1:η3-iPr2-tacn)Li, 3] is presented. Proton sources of widely varying acidity react to protonate the alkylidene ligand, leading to an interesting tantalum−lithium bridging hydride complex in the case of H2. The alkylidene 3 undergoes a series of insertion reactions with unsaturated substrates, such as acetonitrile, carbon monoxide, and carbon disulfide; it also reacts with an acid chloride to yield a tantalum enolate species featuring return of the iPr2-tacn- ligand to a tridentate coordination mode. The incorporated lithium in 3 played an important role, at least structurally, in the chemistry observed." @default.
- W1969722214 created "2016-06-24" @default.
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- W1969722214 date "2002-07-02" @default.
- W1969722214 modified "2023-10-03" @default.
- W1969722214 title "Reactions of a Triazacyclononane-Supported Tantalum−Lithium Bridging Alkylidene with Organic Substrates" @default.
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- W1969722214 doi "https://doi.org/10.1021/om020175c" @default.
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