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• W1969726940 abstract "Nanocrystalline Pr 1− x Zr x O 2− δ (0 ≤ x ≤ 1) and Pr 1− x − y Pd y Zr x O 2− δ ( x = 0.50, y = 0.02) solid solutions have been synthesized by a single step solution combustion method. The whole range of solid solution compositions crystallize in cubic fluorite structure. The lattice parameter ‘ a ’ linearly varied up to x = 1.0. Oxygen-storage capacity (OSC) and redox properties of Pr 1− x Zr x O 2− δ (0.0 ≤ x ≤ 0.8) solid solutions have been investigated by temperature-programmed reduction (TPR) and are compared with those of Ce 1− x Zr x O 2 . Pr 1− x Zr x O 2− δ exhibited H 2 uptake and CO oxidation at a lower temperature than Ce 1− x Zr x O 2 . Small amount of Pd ion ( y = 0.02) substitution was found to bring down the temperature of oxygen release–storage significantly." @default.
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• W1969726940 date "2008-10-01" @default.
• W1969726940 modified "2023-09-23" @default.
• W1969726940 title "Synthesis, structure and oxygen-storage capacity of Pr1−xZrxO2−δ and Pr1−x−yPdyZrxO2−δ" @default.
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• W1969726940 doi "https://doi.org/10.1016/j.materresbull.2007.10.033" @default.
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