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- W1969729348 abstract "In this work, we present a complete and detailed experimental characterization and theoretical study of a variety of coordinated S-nitrosothiols (RSNOs), such as cysteine derivatives, mercaptosuccinic acid, benzyl thiol, and phenyl thiol. Some of them are extremely unstable and sensitive in free form. Strikingly, in contrast with free S-nitrosothiols, we found that, upon coordination to iridium, they become very stable even in aqueous solutions. The study of these coordinated complexes provides further insight on the elucidation of structural aspects dealing with the nature of the S−N bond in RSNOs, a fact which still remains a matter of controversy." @default.
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- W1969729348 date "2008-05-09" @default.
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- W1969729348 title "A Unique Family of Stable and Water-Soluble <i>S</i>-Nitrosothiol Complexes" @default.
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- W1969729348 doi "https://doi.org/10.1021/ic7024999" @default.
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