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- W1969730555 abstract "The morphological structure and the physical properties of free radical synthesized PDMS-PS multiblock polymers have been studied. The polymers were prepared by free radical copolymerization of PDMS macroinitiators with styrene monomer. The length of the PDMS blocks was basically predetermined by the molecular weight of the PDMS macroinitiators which were cationically prepared. However, the PS blocks were formed during the free radical copolymerization. Therefore, the molecular weight and the molecular weight distribution of the PS blocks varied with the PDMS block length at constant styrene conversion level. Hence, the morphology of these polymers as well as the degree of phase separation was altered by the block length of both components. Specific mechanical properties of these polymers were directly related to their morphological structure." @default.
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- W1969730555 date "1989-10-01" @default.
- W1969730555 modified "2023-09-27" @default.
- W1969730555 title "Structure-property behaviour of free radical synthesized polydimethylsiloxane-polystyrene multiblock polymers: 1. Effect of the siloxane block length" @default.
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- W1969730555 doi "https://doi.org/10.1016/0032-3861(89)90349-2" @default.
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