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• W1969736954 abstract "Abstract Reactions of (CF3)2EH (E=P, As) with [Ru3(CO)12] under varying conditions result in hydrogen transfer from ligand to cluster to form trinuclear cluster [Ru3(CO)8(μ-H)2{μ-P(CF3)2}2] 1, double-linked trinuclear clusters [{Ru3(CO)10(μ-H)}2{μ-E(CF3)2}2] (2: E=P; 3: E=As), flat butterfly cluster [Ru4(CO)13{μ-P(CF3)2}2] 4, butterfly clusters [Ru4(CO)12(μ-H)3{μ-E(CF3)2}] (5: E=P; 6: E=As), open-chain clusters [Ru4(CO)14{μ-E(CF3)2}2] (7: E=P; 8: E=As) and square pyramidal clusters [Ru5(CO)15(μ4-ECF3)] (9: E=P; 10: E=As). Cluster 1 contains a triangular Ru plane with two short RuRu bonds bridged by a phosphido and a hydride, respectively. Cluster 2 consists of two coplanar Ru3 triangles linked by two phosphido groups." @default.
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• W1969736954 date "1999-11-01" @default.
• W1969736954 modified "2023-09-28" @default.
• W1969736954 title "The reactions of bis(trifluoromethyl) phosphine and arsine with trinuclear ruthenium carbonyl cluster: molecular structures of the trinuclear and double-linked trinuclear clusters [Ru3(CO)8)(μ-H)2{μ-P(CF3)2}2] and [{Ru3(CO)10(μ-H)}2{μ-P(CF3)2}2]" @default.
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• W1969736954 doi "https://doi.org/10.1016/s0022-328x(99)00370-8" @default.
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