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• W1969752486 abstract "Deviations of experimental millimetre-absorption line shapes from the usual Voigt profile are evidenced for two room-temperature rotational transitions J = 20 ← 19 (502 GHz) and J = 24 ← 23 (602 GHz) of nitrous oxide perturbed by nitrogen and oxygen. These deviations are shown to be due to collisional narrowing processes encompassed by more sophisticated speed-dependent Voigt or Galatry models. The deduced collision-regime line broadening coefficients are compared to their theoretical estimations by a semi-classical formalism. Even with a rough intermolecular potential composed of electrostatic and pair atom–atom interactions, the theoretical linewidths compare favourably with experimental results for both millimetre and infrared absorption." @default.
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• W1969752486 date "2006-01-01" @default.
• W1969752486 modified "2023-10-18" @default.
• W1969752486 title "Detailed profile analysis of millimetre 502 and 602 GHz N₂O–N₂(O₂) lines at room temperature for collisional linewidth determination" @default.
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• W1969752486 doi "https://doi.org/10.1080/03067310600833534" @default.
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