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- W1969754070 abstract "Abstract Methyl esters from vernonia oil containing cis ‐12,13‐epoxy‐cis‐9‐octadecenoate were reacted with acetone in the presence of a boron trifluoride catalyst to yield trans ‐12,13–0‐isopropylidene‐9‐ene derivative I. Epoxidation of the unsaturation followed by reaction with acetone gave the isomeric trans,trans ‐di‐0‐isopropylidene deriva‐tives III of 9,10 :12,13‐tetrahydroxystearates. The carboxylic acids of III were converted to vinyl esters and subsequent hydrolysis of the isopropy‐lidene groups with boric acid produced vinyl threo ‐9,10 threo ‐12,13‐tetrahydroxystearates. By the same sequence of reactions monoepoxidized methyl linoleate yielded an optically inactive de‐rivative which had identical refractive index, IR spectrum, and GLC data to III from vernonia methyl esters." @default.
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- W1969754070 date "1967-11-01" @default.
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- W1969754070 title "Synthesis of vinyl threo‐9, 10‐threo‐12, 13‐tetrahydroxystearates" @default.
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- W1969754070 doi "https://doi.org/10.1007/bf02680036" @default.
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