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- W1969778049 abstract "A crossed beam study of CO+ production from the C+ + O2 reaction at a collision energy of 0.57 eV is presented. Very clear collision complex dynamics are observed which are shown to be consistent with the decay of a transient complex having a lifetime of approximately 0.5 ps. An analysis of the reactive scattering using an adiabatic state correlation diagram indicates that the formation of X-state CO2+ by insertion of C+ into the O2 bond is accessible from the reagents and correlates adiabatically with ground-state products. The average kinetic energy release is approximately 23% of the available energy. A comparison of the present data with the chemiluminescent studies of A-state production of CO+ indicates that the dominant channels at low energies are production of ground-state CO+ through the X2Πg and a4Πu state of CO2+." @default.
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- W1969778049 date "1986-03-01" @default.
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- W1969778049 title "Collision complex formation in the low-energy dynamics of the C+ + O2 reaction" @default.
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- W1969778049 doi "https://doi.org/10.1016/0009-2614(86)85088-6" @default.
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