Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969780233> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W1969780233 endingPage "2939" @default.
- W1969780233 startingPage "2933" @default.
- W1969780233 abstract "Abstract [Bu 4 N] 2 [Ni(btdt) 2 ] ( 1 ) ({btdt} 2– = 2,1,3‐benzenethiadiazole‐5,6‐dithiolate) was synthesized by treating one equivalent of NiCl 2 · 6H 2 O with two equivalents of H 2 btdt in MeOH in the presence of NaOH under nitrogen, and then obtaining a precipitate by adding tetrabutylammonium bromide. When the same reaction is carried out under ambient conditions, it yields the trans ‐disulfinate complex [Bu 4 N] 2 [Ni(btdtO 2 ) 2 ] · H 2 O ( 2 ) along with complex 1 . Complex 1 crystallizes in the triclinic space group P $bar {1}$ , whereas complex 2 crystallizes in the monoclinic space group C 2/ c . The Ni II ion, coordinated with four sulfur atoms present in complex 1 , shows almost square‐planar geometry, but trans ‐disulfinate complex 2 shows distorted square‐planar geometry around the Ni II ion with a nonplanar molecular structure. Oxygen atoms of the sulfinates are involved in C–H ··· O and O–H ··· O hydrogen‐bonding interactions, which might be important factors for the nonplanarity of complex 2 . Complex 1 undergoes a reversible oxidation (Δ E = 0.09 V) at E 1/2 = +0.22 V vs. Ag/AgCl and an irreversible oxidation at +0.77 V, whereas complex 2 shows quasi‐reversible oxidation at E 1/2 = +0.50 V vs. Ag/AgCl in acetonitrile solution." @default.
- W1969780233 created "2016-06-24" @default.
- W1969780233 creator A5004375913 @default.
- W1969780233 creator A5070564138 @default.
- W1969780233 date "2012-04-17" @default.
- W1969780233 modified "2023-10-10" @default.
- W1969780233 title "Sulfur Oxygenation of [Ni(btdt) <sub>2</sub> ] <sup>2–</sup> by Aerial Oxidation under Ambient Conditions – Syntheses, Crystal Structures, and Properties of [Bu <sub>4</sub> N] <sub>2</sub> [Ni(btdt) <sub>2</sub> ] and [Bu <sub>4</sub> N] <sub>2</sub> [Ni(btdtO <sub>2</sub> ) <sub>2</sub> ]·H <sub>2</sub> O ({btdt} <sup>2–</sup> = 2,1,3‐Benzenethiadiazole‐5,6‐dithiolate)" @default.
- W1969780233 cites W1567007829 @default.
- W1969780233 cites W1963595494 @default.
- W1969780233 cites W1963815948 @default.
- W1969780233 cites W1968089295 @default.
- W1969780233 cites W1969460721 @default.
- W1969780233 cites W1974493671 @default.
- W1969780233 cites W1975986084 @default.
- W1969780233 cites W1978651261 @default.
- W1969780233 cites W1979219614 @default.
- W1969780233 cites W1979889508 @default.
- W1969780233 cites W1981125958 @default.
- W1969780233 cites W1993637922 @default.
- W1969780233 cites W2002535796 @default.
- W1969780233 cites W2012551353 @default.
- W1969780233 cites W2016605957 @default.
- W1969780233 cites W2022186648 @default.
- W1969780233 cites W2033930781 @default.
- W1969780233 cites W2037381429 @default.
- W1969780233 cites W2045555811 @default.
- W1969780233 cites W2049445233 @default.
- W1969780233 cites W2049774299 @default.
- W1969780233 cites W2052315017 @default.
- W1969780233 cites W2055572075 @default.
- W1969780233 cites W2071901579 @default.
- W1969780233 cites W2087642816 @default.
- W1969780233 cites W2097239055 @default.
- W1969780233 cites W2131350133 @default.
- W1969780233 cites W2149531858 @default.
- W1969780233 cites W2190333786 @default.
- W1969780233 cites W2331636208 @default.
- W1969780233 cites W2949527046 @default.
- W1969780233 cites W2949913820 @default.
- W1969780233 doi "https://doi.org/10.1002/ejic.201101426" @default.
- W1969780233 hasPublicationYear "2012" @default.
- W1969780233 type Work @default.
- W1969780233 sameAs 1969780233 @default.
- W1969780233 citedByCount "8" @default.
- W1969780233 countsByYear W19697802332013 @default.
- W1969780233 countsByYear W19697802332017 @default.
- W1969780233 countsByYear W19697802332018 @default.
- W1969780233 countsByYear W19697802332019 @default.
- W1969780233 countsByYear W19697802332020 @default.
- W1969780233 countsByYear W19697802332022 @default.
- W1969780233 crossrefType "journal-article" @default.
- W1969780233 hasAuthorship W1969780233A5004375913 @default.
- W1969780233 hasAuthorship W1969780233A5070564138 @default.
- W1969780233 hasConcept C115624301 @default.
- W1969780233 hasConcept C178790620 @default.
- W1969780233 hasConcept C179104552 @default.
- W1969780233 hasConcept C185592680 @default.
- W1969780233 hasConcept C2776300020 @default.
- W1969780233 hasConcept C2777463227 @default.
- W1969780233 hasConcept C42228675 @default.
- W1969780233 hasConcept C61276311 @default.
- W1969780233 hasConcept C8010536 @default.
- W1969780233 hasConceptScore W1969780233C115624301 @default.
- W1969780233 hasConceptScore W1969780233C178790620 @default.
- W1969780233 hasConceptScore W1969780233C179104552 @default.
- W1969780233 hasConceptScore W1969780233C185592680 @default.
- W1969780233 hasConceptScore W1969780233C2776300020 @default.
- W1969780233 hasConceptScore W1969780233C2777463227 @default.
- W1969780233 hasConceptScore W1969780233C42228675 @default.
- W1969780233 hasConceptScore W1969780233C61276311 @default.
- W1969780233 hasConceptScore W1969780233C8010536 @default.
- W1969780233 hasIssue "17" @default.
- W1969780233 hasLocation W19697802331 @default.
- W1969780233 hasOpenAccess W1969780233 @default.
- W1969780233 hasPrimaryLocation W19697802331 @default.
- W1969780233 hasRelatedWork W1550031554 @default.
- W1969780233 hasRelatedWork W1998057223 @default.
- W1969780233 hasRelatedWork W2009826639 @default.
- W1969780233 hasRelatedWork W2070844528 @default.
- W1969780233 hasRelatedWork W2260173655 @default.
- W1969780233 hasRelatedWork W2283894052 @default.
- W1969780233 hasRelatedWork W2395756852 @default.
- W1969780233 hasRelatedWork W2949498525 @default.
- W1969780233 hasRelatedWork W2951503600 @default.
- W1969780233 hasRelatedWork W2952169498 @default.
- W1969780233 hasVolume "2012" @default.
- W1969780233 isParatext "false" @default.
- W1969780233 isRetracted "false" @default.
- W1969780233 magId "1969780233" @default.
- W1969780233 workType "article" @default.