Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969785955> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W1969785955 endingPage "42" @default.
- W1969785955 startingPage "39" @default.
- W1969785955 abstract "Abstract The kinetics of oxidation of bivalent manganese to the heptavalent state peroxomonophosphoric acid was investigated spectrophotometrically in a perchloric acid medium. The reaction was found to be negligible in absence of a suitable catalyst. In the presence of traces of Co(II), the reaction is found to proceed with a measurable speed following first order kinetics and binomial dependence on [Mn(II)], first order in [Co(II)] and fractional order dependence on [PMPA] and [H+]. The reaction was found to be autocatalytic, the Mn(IV) formed as a transient reactive species catalysing its further oxidation to Mn(VII). A mechanism consistent with the observed kinetics is proposed and the rate law derived." @default.
- W1969785955 created "2016-06-24" @default.
- W1969785955 creator A5002915910 @default.
- W1969785955 creator A5050408699 @default.
- W1969785955 creator A5069932737 @default.
- W1969785955 creator A5079241942 @default.
- W1969785955 date "1987-07-01" @default.
- W1969785955 modified "2023-09-25" @default.
- W1969785955 title "Oxidation of bivalent manganese by peroxomonophosphoric acid catalysed by cobalt(II) - a kinetic study" @default.
- W1969785955 cites W2074705535 @default.
- W1969785955 cites W2088633808 @default.
- W1969785955 cites W2329457176 @default.
- W1969785955 cites W3136729721 @default.
- W1969785955 cites W48337641 @default.
- W1969785955 doi "https://doi.org/10.1016/s0020-1693(00)87904-9" @default.
- W1969785955 hasPublicationYear "1987" @default.
- W1969785955 type Work @default.
- W1969785955 sameAs 1969785955 @default.
- W1969785955 citedByCount "3" @default.
- W1969785955 crossrefType "journal-article" @default.
- W1969785955 hasAuthorship W1969785955A5002915910 @default.
- W1969785955 hasAuthorship W1969785955A5050408699 @default.
- W1969785955 hasAuthorship W1969785955A5069932737 @default.
- W1969785955 hasAuthorship W1969785955A5079241942 @default.
- W1969785955 hasConcept C121332964 @default.
- W1969785955 hasConcept C135889238 @default.
- W1969785955 hasConcept C161790260 @default.
- W1969785955 hasConcept C178790620 @default.
- W1969785955 hasConcept C179104552 @default.
- W1969785955 hasConcept C185592680 @default.
- W1969785955 hasConcept C2776620830 @default.
- W1969785955 hasConcept C515602321 @default.
- W1969785955 hasConcept C528890316 @default.
- W1969785955 hasConcept C544153396 @default.
- W1969785955 hasConcept C62520636 @default.
- W1969785955 hasConceptScore W1969785955C121332964 @default.
- W1969785955 hasConceptScore W1969785955C135889238 @default.
- W1969785955 hasConceptScore W1969785955C161790260 @default.
- W1969785955 hasConceptScore W1969785955C178790620 @default.
- W1969785955 hasConceptScore W1969785955C179104552 @default.
- W1969785955 hasConceptScore W1969785955C185592680 @default.
- W1969785955 hasConceptScore W1969785955C2776620830 @default.
- W1969785955 hasConceptScore W1969785955C515602321 @default.
- W1969785955 hasConceptScore W1969785955C528890316 @default.
- W1969785955 hasConceptScore W1969785955C544153396 @default.
- W1969785955 hasConceptScore W1969785955C62520636 @default.
- W1969785955 hasIssue "1" @default.
- W1969785955 hasLocation W19697859551 @default.
- W1969785955 hasOpenAccess W1969785955 @default.
- W1969785955 hasPrimaryLocation W19697859551 @default.
- W1969785955 hasRelatedWork W1974264739 @default.
- W1969785955 hasRelatedWork W1992738016 @default.
- W1969785955 hasRelatedWork W2000881355 @default.
- W1969785955 hasRelatedWork W2026105967 @default.
- W1969785955 hasRelatedWork W2042024419 @default.
- W1969785955 hasRelatedWork W2741884853 @default.
- W1969785955 hasRelatedWork W2952405670 @default.
- W1969785955 hasRelatedWork W2995594236 @default.
- W1969785955 hasRelatedWork W4200544918 @default.
- W1969785955 hasRelatedWork W60976972 @default.
- W1969785955 hasVolume "131" @default.
- W1969785955 isParatext "false" @default.
- W1969785955 isRetracted "false" @default.
- W1969785955 magId "1969785955" @default.
- W1969785955 workType "article" @default.