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W1969827909 abstract "Abstract The kinetics of the gas‐phase reactions of O( 3 P) atoms with ( Z )‐CHClCHCl, CCl 2 CH 2 , CCl 2 CCl 2 and ( E / Z )‐CFClCHCl were studied at 298 K using a discharge flow tube system. The overall rate constants based on the measured afterglow reactions were (2.0 ± 0.2) × 10 −13 , (11.3 ± 0.9) × 10 −13 , (1.9 ± 0.3) × 10 −13 , and (1.4 ± 0.3) × 10 −14 , respectively, all in units of cm 3 molecule −1 sec −1 . The experiments were carried out under pseudo‐first‐order conditions with [O( 3 P)] 0 ≪ [chloroethene]. Halogen substitution in the alkenes is discussed in terms of reactivity with O( 3 P) and its relation to the ionization potential and the reactivity with OH radicals. Copyright © 2006 John Wiley & Sons, Ltd." @default.
W1969827909 created "2016-06-24" @default.
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W1969827909 date "2006-11-01" @default.
W1969827909 modified "2023-10-14" @default.
W1969827909 title "Gas-phase kinetics of the reactions of O(3P) atoms with (Z)-CHClCHCl, CCl2CH2, CCl2CCl2 and (E/Z)-CFClCHCl at 298 K" @default.
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W1969827909 doi "https://doi.org/10.1002/poc.1070" @default.
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