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- W1969847362 abstract "The gamma radiolysis of nitrogen and sulfur heterocyclics having one or more nitrogen or sulfur atoms in five- and six-membered rings was studied. G values are given for the major gaseous products identified by gas chromatography for the radiolyses of pyrrole, pyrazole, imidazole, 1,2,4-triazole, tetrazole, pyrazine, pyrimidine, 1,3,5-triazine, benzotriazole, thiazole, isothiazole, and thiophene. The principal gaseous product formed during the γ-radiation of five- and six-membered nitrogen heterocyclics was hydrogen except that compounds having two adjacent nitrogen atoms in the ring produced large amounts of nitrogen and other gaseous products. When the N atoms are separated by carbon atoms, no nitrogen gas is produced and the G values for gas production are very low. Thiophene has greater stability to radiation than pyrrole as far as gas production is concerned. However, the introduction of a second heteroatom (nitrogen in the case of thiazole and isothiazole) in the five-membered ring containing sulfur..." @default.
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- W1969847362 date "1973-10-01" @default.
- W1969847362 modified "2023-10-16" @default.
- W1969847362 title "Radiation Chemistry of Nitrogen and Sulfur Heterocyclics" @default.
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- W1969847362 doi "https://doi.org/10.2307/3573792" @default.
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