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- W1969855008 abstract "The radical induced oxidation of acetaldehyde in the photo-oxidation of azoethane was studied at 28°, 118° and 152°. In most experiments the acetaldehyde built up was substantially less than 0.8 mm, the observed limiting value at high conversion. Major products in the radical induced oxidation of acetaldehyde are carbon dioxide and methanol; minor products are carbon monoxide and (per)acetic acid. Formaldehyde was positively identified as a reaction product. It is proposed that the formation of the reaction products proceeds via the acetyl radical:CH3CHO + RCH2O· CH3CO· + RCH2OH [8]CH3CO· ·CH3 + CO [9]CH3CO· + O2 CH3O· + CO2 [11]CH3CO· + O2 CH3CO3· [12]CH3CO3· + AH CH3CO3H + A· [16]where AH stands for acetaldehyde and azoethane. The methoxy radicals will form methanol and formaldehyde.Reaction [11] does not necessarily proceed in one step. At 28° k9/k11 = (4±2) · 1013 molec · cm −3." @default.
- W1969855008 created "2016-06-24" @default.
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- W1969855008 date "2010-09-02" @default.
- W1969855008 modified "2023-09-26" @default.
- W1969855008 title "The radical induced oxidation of acetaldehyde" @default.
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- W1969855008 doi "https://doi.org/10.1002/recl.19640830907" @default.
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