Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969867519> ?p ?o ?g. }
- W1969867519 endingPage "5260" @default.
- W1969867519 startingPage "5243" @default.
- W1969867519 abstract "A new method of synthesis of homo- and heteroleptic cis bis-chelated Pd(II) species by a transmetalation reaction of the ortho-mercurated 2-[tricarbonyl(η6-phenyl)chromium]pyridine with a series of bis(μ-chloro) palladacyclic aromatic compounds in the presence of a large excess of the chloride salt [NMe4]Cl is reported. These (CO)3Cr-bound bis-chelated Pd(II) species can be designed for the preparation of enantiopure planar chiral cyclopalladated (η6-arene)Cr(CO)3 complexes. The study of the mechanism of this transmetalation reaction reveals the key role of the excess of chloride salt, which is necessary for the isolation of persistent heteroleptic bis-chelated Pd(II) complexes. This method was further applied to the synthesis of highly enantioenriched (+) and (−) samples of the ortho-chloropalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine, whose enantiopurity was assessed with the aid of diamagnetic Λ and Δ TRISPHAT salts used as chiral shift 1H NMR agents. The absolute configurations of the two enantioenriched complexes were obtained from the corresponding absolute structures determined by X-ray diffraction analyses. The molecular structures of six new heteroleptic bis-chelated Pd(II) complexes are reported." @default.
- W1969867519 created "2016-06-24" @default.
- W1969867519 creator A5017402548 @default.
- W1969867519 creator A5037856739 @default.
- W1969867519 creator A5054675313 @default.
- W1969867519 creator A5055019395 @default.
- W1969867519 creator A5072497114 @default.
- W1969867519 creator A5076771956 @default.
- W1969867519 creator A5085027154 @default.
- W1969867519 date "2003-11-12" @default.
- W1969867519 modified "2023-10-16" @default.
- W1969867519 title "Chloride-Promoted Synthesis of Cis Bis-Chelated Palladium(II) Complexes from Ortho-Mercurated Tricarbonyl(η<sup>6</sup>-arene)chromium Complexes" @default.
- W1969867519 cites W1501629435 @default.
- W1969867519 cites W1595147398 @default.
- W1969867519 cites W1820304200 @default.
- W1969867519 cites W1963488788 @default.
- W1969867519 cites W1964545734 @default.
- W1969867519 cites W1966878861 @default.
- W1969867519 cites W1967405157 @default.
- W1969867519 cites W1969822178 @default.
- W1969867519 cites W1970486780 @default.
- W1969867519 cites W1970530158 @default.
- W1969867519 cites W1970530829 @default.
- W1969867519 cites W1973053405 @default.
- W1969867519 cites W1973114122 @default.
- W1969867519 cites W1976870387 @default.
- W1969867519 cites W1977982687 @default.
- W1969867519 cites W1989296710 @default.
- W1969867519 cites W1993460190 @default.
- W1969867519 cites W1994352751 @default.
- W1969867519 cites W1997344293 @default.
- W1969867519 cites W1998040694 @default.
- W1969867519 cites W2002736443 @default.
- W1969867519 cites W2009815261 @default.
- W1969867519 cites W2011182748 @default.
- W1969867519 cites W2011841410 @default.
- W1969867519 cites W2012137420 @default.
- W1969867519 cites W2012673046 @default.
- W1969867519 cites W2015792310 @default.
- W1969867519 cites W2016281653 @default.
- W1969867519 cites W2017059239 @default.
- W1969867519 cites W2018429140 @default.
- W1969867519 cites W2019047587 @default.
- W1969867519 cites W2019929300 @default.
- W1969867519 cites W2020987326 @default.
- W1969867519 cites W2021455561 @default.
- W1969867519 cites W2025658574 @default.
- W1969867519 cites W2027406375 @default.
- W1969867519 cites W2031150214 @default.
- W1969867519 cites W2031312091 @default.
- W1969867519 cites W2032832240 @default.
- W1969867519 cites W2035364787 @default.
- W1969867519 cites W2035443159 @default.
- W1969867519 cites W2036710646 @default.
- W1969867519 cites W2037048025 @default.
- W1969867519 cites W2041392298 @default.
- W1969867519 cites W2041734311 @default.
- W1969867519 cites W2043498492 @default.
- W1969867519 cites W2047425960 @default.
- W1969867519 cites W2051943093 @default.
- W1969867519 cites W2052838994 @default.
- W1969867519 cites W2053845854 @default.
- W1969867519 cites W2060342616 @default.
- W1969867519 cites W2062624137 @default.
- W1969867519 cites W2065269455 @default.
- W1969867519 cites W2069938803 @default.
- W1969867519 cites W2074197403 @default.
- W1969867519 cites W2076278353 @default.
- W1969867519 cites W2077750577 @default.
- W1969867519 cites W2082605077 @default.
- W1969867519 cites W2084523269 @default.
- W1969867519 cites W2084646836 @default.
- W1969867519 cites W2085792721 @default.
- W1969867519 cites W2090857541 @default.
- W1969867519 cites W2091090266 @default.
- W1969867519 cites W2093671753 @default.
- W1969867519 cites W2109511767 @default.
- W1969867519 cites W2114312014 @default.
- W1969867519 cites W2135838290 @default.
- W1969867519 cites W2139952730 @default.
- W1969867519 cites W2154946858 @default.
- W1969867519 cites W2162328714 @default.
- W1969867519 cites W2166602283 @default.
- W1969867519 cites W2322005241 @default.
- W1969867519 cites W2323435594 @default.
- W1969867519 cites W2325286049 @default.
- W1969867519 cites W2328919977 @default.
- W1969867519 cites W2329764185 @default.
- W1969867519 cites W2331526811 @default.
- W1969867519 cites W2485190808 @default.
- W1969867519 cites W2521482146 @default.
- W1969867519 cites W2941461835 @default.
- W1969867519 cites W2949127834 @default.
- W1969867519 cites W2950550876 @default.
- W1969867519 cites W2952959785 @default.
- W1969867519 cites W4206204255 @default.
- W1969867519 cites W4231185135 @default.
- W1969867519 cites W4232865717 @default.