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- W1969870852 abstract "An investigation of the reaction conditions influence on the self-assembling of Ru2(CO3)43− paddle wheel precursors and Co2+ ions in aqueous solution has resulted in a series of Co–Ru2 hetero-metallic complexes with different composition and dimensionality, namely [K1/3{Co(H2O)6}4/3{Ru2(CO3)4(H2O)2}]·2H2O (1), [KCo(H2O)5Ru2(CO3)4]·5H2O (2), and [KCo(H2O)4Ru2(CO3)4]·H2O (3). These complexes exhibit dimensional diversity due to the various linking modes of Co2+ ions. X-Ray structural analysis reveals that complex 1 is composed of ionic crystals with the Ru2(CO3)43− : Co(H2O)62+ : K+ ratio of 3 : 4 : 1. For complex 2, one water of each Co(H2O)62+ is substituted by one oxygen of Ru2(CO3)43− forming [Co(H2O)5Ru2(CO3)4]−, then the neighboring Ru2(CO3)43− units are connected to each other through the remaining two carbonate oxygen atoms forming a negative square-grid layer [Co(H2O)5Ru2(CO3)4]nn−. In complex 3, two water molecules of each Co(H2O)62+ are substituted by the oxygen atoms of Ru2(CO3)43− units, which are connected to each other forming the square-grid layer [Ru2(CO3)4]n3n− similar to that in 2, then Co(H2O)42+ ions bond to neighboring [Ru2(CO3)4]n3n− layers in a cis mode forming the three-dimensional network [Co(H2O)4Ru2(CO3)4]nn−. Complex 2 exhibits ferromagnetic coupling between Ru25+ and Co2+, and long-range ordering is observed below 5.0 K. In contrast, complex 3 with a 3-D sublattice displays spin-glass behavior with the coexistence of spin-canting with magnetic ordering at 4.7 K." @default.
- W1969870852 created "2016-06-24" @default.
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- W1969870852 date "2013-01-01" @default.
- W1969870852 modified "2023-09-25" @default.
- W1969870852 title "Heterometallic Co(ii)–Ru2(ii,iii) carbonates: from discrete ionic crystals to three-dimensional network" @default.
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- W1969870852 doi "https://doi.org/10.1039/c3ce40517f" @default.
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