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- W1969881589 abstract "The strontium vanadophosphate, belonging to the seriesAV2O(PO4)2withA= Cd, Ca, Sr has been synthesized. Its single-crystal X-Ray study shows its isotypism with the cadmium and calcium phases. It crystallizes in the space groupPnmawitha= 14.220(1) Å,b= 6.5138(6) Å, andc= 7.5166(8) Å,Z= 4, andR= 0.039. In its structure, built up from [VIIIO2]∞rutile chains connected through VO6octahedra and PO4tetrahedra, the geometry of the polyhedra is very close to that obtained for the Cd and Ca phases. The main difference deals with the V(2)–V(2) intrachains distances that increase significantly with the size of theAcation. The study of the magnetic susceptibility of the three monophosphates (A= Cd, Ca, Sr) evidences a narrow transition of 20 K from a paramagnetic to antiferromagnetic state. This behavior is in contrast with that of the VIIIPO4phase that also exhibits isolated rutile chains but shows a broad transition spreading over 100 K. This difference is explained by the presence of additionnal VO6octahedra that may weaken the unidimensional character of these phosphates compared to VPO4." @default.
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- W1969881589 date "1996-12-01" @default.
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- W1969881589 title "The V(III) Monophosphate Series AV2O(PO4)2withA= Cd, Ca, Sr: Structure and Magnetism" @default.
- W1969881589 doi "https://doi.org/10.1006/jssc.1996.0390" @default.
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