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- W1969917008 abstract "The kinetic and thermodynamic aspects of a two-intermediate scheme proposed previously to describe the catalytic decomposition of H2O2 by iron(III)-based catalysts have been investigated. Under non-stationary conditions there is a partial transfer of free energy liberated in the decomposition of H2O2 to assist the formation of the secondary intermediate, CII. The accumulation of CII can be driven, for a limited period of time, against a free-energy gradient in respect of the initial reactants (the free catalyst E and H2O2). The kinetic condition for coupling is the reversal of sign of the net rate of formation of the precursor of CII(CI) from E and H2O2. Kinetic and thermodynamic aspects of the occurrence of coupling between an endergonic and an exergonic process are discussed in the general case." @default.
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- W1969917008 date "1988-01-01" @default.
- W1969917008 modified "2023-10-02" @default.
- W1969917008 title "Coupling of free energies in the formation of intermediates during the catalytic decomposition of H2O2" @default.
- W1969917008 doi "https://doi.org/10.1039/f19888404145" @default.
- W1969917008 hasPublicationYear "1988" @default.
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