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- W1969924689 abstract "The excited triplet state of 1-nitronaphthalene (31NN*) reacts with OH with a second-order reaction rate constant of (1.66 ± 0.08)×107 M-1 s−1 (μ ± σ). The reaction yields the ·OH radical and the radical anion 1NN−·. In aerated solution, the radical 1NN−· would react with O2 to finally produce H2O2 upon hydroperoxide/superoxide disproportionation. The photolysis of H2O2 is another potential source of ·OH, but such a pathway would be a minor one in circumneutral (pH 6.5) or in basic solution ([OH‒] = 0.3-0.5 M). The oxidation of H2O by 31NN*, with rate constant 3.8 ± 0.3 M−1 s−1, could be the main ·OH source at pH 6.5." @default.
- W1969924689 created "2016-06-24" @default.
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- W1969924689 date "2011-11-01" @default.
- W1969924689 modified "2023-10-05" @default.
- W1969924689 title "Formation of hydroxyl radicals by irradiated 1-nitronaphthalene (1NN): oxidation of hydroxyl ions and water by the 1NN triplet state" @default.
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- W1969924689 doi "https://doi.org/10.1039/c1pp05216k" @default.
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