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- W1969926221 abstract "An efficient procedure for the highly selective oxidation of leucomycines to the corresponding 16-membered 9- and 13-oxo macrolides using hypervalent iodinates is presented. Both the Dess-Martin periodinane (DMP) and polymer-bound 2-iodoxybenzoic acid (IBX) show clear advantages over the previously employed manganese dioxide. Key intermediates for a variety of further chemical derivatization methods (2a, 2b) are obtained in very good yields without the requirement of protecting groups." @default.
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- W1969926221 date "2005-01-01" @default.
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- W1969926221 title "Efficient Synthesis of 9- and 13-Oxo Leucomycin Derivatives Using Hypervalent Iodine Reagents in Solution and on Solid Support" @default.
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- W1969926221 doi "https://doi.org/10.1021/np049728+" @default.
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