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- W1969931072 abstract "The thiophene HDS activities of phosphorus-containing Co and Co&z,sbnd;Mo sulfide catalysts supported on γ-Al2O3 and activated carbon were measured at atmospheric pressure. Phosphorus decreased the thiophene HDS activity of the carbon-supported catalysts considerably but did not affect the activity of the alumina-supported catalysts. From XPS it was inferred that phosphorus improves the dispersion of the cobalt phase in the oxidic precursor state of both the carbon- and alumina-supported catalysts. In the sulfided state the interaction between phosphorus and the metal sulfide phase appeared to depend on the support. In the sulfided carbon-supported catalysts, phosphorus formed a Co-phosphate phase, which is responsible for the decrease in HDS activity, while on alumina phosphorus did not influence the structure of the metal sulfide phase." @default.
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- W1969931072 date "1991-04-01" @default.
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- W1969931072 title "The influence of phosphorus on the structure and hydrodesulfurization activity of sulfided Co and Co$z,sbnd;Mo catalysts supported on carbon and alumina" @default.
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- W1969931072 doi "https://doi.org/10.1016/0021-9517(91)90313-s" @default.
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