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- W1969934963 abstract "The ultraviolet He(I) and He(II) photoelectron (UP) spectra have been recorded for the dinuclear d7-metal carbonyl complexes [(CO)5M-M′(CO)3(i-PrNCHCHN-i-Pr)], where M = Mn, M′ = Re; M = Re, M′ = Mn; M = M′ = Mn; M = M′ = Re. The observed vertical ionization energies (IE's) of these four complexes are assigned to metal d orbitals, the ligand orbitals, the metal-metal σb orbital with the aid of semi-empirical molecular orbital (MO) calculations, consideration of He(I)/He(II) intensity ratios, and comparison with data for related complexes. The IE's of the σb (M = M′) orbital of these complexes are 6.95 eV (M = M′ = Mn), 7.19 eV (M = Re, M′ = Mn), 7.15 eV (M = Mn, M′ = Re) and 7.03 eV (M = M′ = Re), respectively. These data and other UP results are of importance for the interpretation of the photochemical behaviour of these complexes." @default.
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- W1969934963 date "1985-07-01" @default.
- W1969934963 modified "2023-10-03" @default.
- W1969934963 title "He(I) and He(II) photoelectron spectra of the four metal-metal bonded complexes [(CO)5M-M′(CO)3(1,4-i-Pr2-1,4-diaza-13-butediene)] (M = M′ = Mn or Re; M = Mn, M′ = Re; M = Re, M′ = Mn)" @default.
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- W1969934963 doi "https://doi.org/10.1016/0022-328x(85)80149-2" @default.
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