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• W1969955905 abstract "The self-assembly of cyano-bridged discrete coordination architectures and polymeric coordination networks based on 〚M(CN)8〛3–/4– (M = Mo and W) molecular building blocks has been systematically investigated in order to obtain some basic information useful for crystal engineering of supramolecular coordination networks. The research is illustrated by concentrating on the superstructural diversity that has been exhibited in 0D architectures generated by cis and trans octahedral precursors, 1D and 2D architectures generated by Cu(II) centres, as well as in 2D structure generated by octahedral node of 〚Mn(H2O)6〛2+ and geometrically anisotropic 〚W(CN)6(bpy)〛2– (bpy = 2,2’-bipyridine). L’auto-assemblage d’architectures de coordination discrètes à ponts cyanure et de réseaux de coordination polymériques basés sur des briques moléculaires 〚M(CN)8〛3–/4– (M = Mo et W) a été étudié de manière systématique pour obtenir des informations de base utiles en ingénierie cristalline de réseaux de coordination supramoléculaires. Cette recherche est illustrée en considérant plus particulièrement la diversité structurale relevée dans des architectures 0D engendrées par des précurseurs octaédriques cis et trans, dans des architectures 1D et 2D engendrées par des centres Cu(II), ainsi que dans des structures 2D basées sur des nœuds octaédriques de 〚Mn(H2O)6〛2+ et de 〚W(CN)6(bpy)〛2– (bpy = 2,2’-bipyridine) géométriquement anisotrope." @default.
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• W1969955905 date "2002-10-01" @default.
• W1969955905 modified "2023-09-24" @default.
• W1969955905 title "Supramolecular networks based on octacyanometallates of Mo and W" @default.
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• W1969955905 doi "https://doi.org/10.1016/s1631-0748(02)01428-5" @default.
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