Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969968688> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W1969968688 endingPage "864" @default.
- W1969968688 startingPage "853" @default.
- W1969968688 abstract "Abstract Glycerol and d , l -homocysteine thiolactone – two bio-based building blocks – were used to prepare a bis-cyclic AA′ monomer (or coupler) with an ethylene carbonate and a thiolactone ring linked by an O-methyl urethane spacer. On reaction of this monomer with diamines at 70 °C poly(amide urethane)s with pendant thioethyl and hydroxymethyl side groups are produced in one step. Monodisperse diamines of low molecular weight (MW), monodisperse amino telechelic poly(ethylene oxide) (MW = 897.10) and polydisperse amino telechelic polytetrahydrofuran (Mn = 1100) were used as amine building blocks. By reaction of the coupler with diamines at room temperature only the thiolactone ring is converted. Consequently, a bis(ethylene carbonate) bis(thiol) is obtained if one equivalent diamine is reacted with two equivalents of coupler. Reaction of this intermediate with a second diamine leads to poly(amide urethane)s with pendant thioethyl and hydroxymethyl side groups and alternating amine building blocks. Post-polymerization modification of thiol side groups leads to polymers with designed properties. The microstructure of the obtained polymers was proven by 1H NMR and Raman spectroscopy; the molecular weights were determined by size exclusion chromatography." @default.
- W1969968688 created "2016-06-24" @default.
- W1969968688 creator A5057321597 @default.
- W1969968688 creator A5071237071 @default.
- W1969968688 creator A5089780896 @default.
- W1969968688 date "2013-04-01" @default.
- W1969968688 modified "2023-10-17" @default.
- W1969968688 title "Poly(amide urethane)s with functional/reactive side groups based on a bis-cyclic bio-based monomer/coupling agent" @default.
- W1969968688 cites W1971333136 @default.
- W1969968688 cites W1977174044 @default.
- W1969968688 cites W1978437431 @default.
- W1969968688 cites W1987284992 @default.
- W1969968688 cites W1994304824 @default.
- W1969968688 cites W1998197731 @default.
- W1969968688 cites W2003695923 @default.
- W1969968688 cites W2008005683 @default.
- W1969968688 cites W2011438015 @default.
- W1969968688 cites W2013458139 @default.
- W1969968688 cites W2013961091 @default.
- W1969968688 cites W2016642501 @default.
- W1969968688 cites W2034565712 @default.
- W1969968688 cites W2034604498 @default.
- W1969968688 cites W2047602927 @default.
- W1969968688 cites W2052586142 @default.
- W1969968688 cites W2059384551 @default.
- W1969968688 cites W2059688822 @default.
- W1969968688 cites W2070152736 @default.
- W1969968688 cites W2080159816 @default.
- W1969968688 cites W2081065586 @default.
- W1969968688 cites W2083712314 @default.
- W1969968688 cites W2094321917 @default.
- W1969968688 cites W2129039632 @default.
- W1969968688 cites W2131200077 @default.
- W1969968688 cites W2168422917 @default.
- W1969968688 cites W2313538383 @default.
- W1969968688 doi "https://doi.org/10.1016/j.eurpolymj.2012.10.024" @default.
- W1969968688 hasPublicationYear "2013" @default.
- W1969968688 type Work @default.
- W1969968688 sameAs 1969968688 @default.
- W1969968688 citedByCount "23" @default.
- W1969968688 countsByYear W19699686882013 @default.
- W1969968688 countsByYear W19699686882014 @default.
- W1969968688 countsByYear W19699686882015 @default.
- W1969968688 countsByYear W19699686882016 @default.
- W1969968688 countsByYear W19699686882017 @default.
- W1969968688 countsByYear W19699686882018 @default.
- W1969968688 countsByYear W19699686882019 @default.
- W1969968688 countsByYear W19699686882020 @default.
- W1969968688 countsByYear W19699686882021 @default.
- W1969968688 countsByYear W19699686882022 @default.
- W1969968688 crossrefType "journal-article" @default.
- W1969968688 hasAuthorship W1969968688A5057321597 @default.
- W1969968688 hasAuthorship W1969968688A5071237071 @default.
- W1969968688 hasAuthorship W1969968688A5089780896 @default.
- W1969968688 hasConcept C131584629 @default.
- W1969968688 hasConcept C159985019 @default.
- W1969968688 hasConcept C166940927 @default.
- W1969968688 hasConcept C178790620 @default.
- W1969968688 hasConcept C185592680 @default.
- W1969968688 hasConcept C188027245 @default.
- W1969968688 hasConcept C192562407 @default.
- W1969968688 hasConcept C21951064 @default.
- W1969968688 hasConcept C2778439535 @default.
- W1969968688 hasConcept C521977710 @default.
- W1969968688 hasConceptScore W1969968688C131584629 @default.
- W1969968688 hasConceptScore W1969968688C159985019 @default.
- W1969968688 hasConceptScore W1969968688C166940927 @default.
- W1969968688 hasConceptScore W1969968688C178790620 @default.
- W1969968688 hasConceptScore W1969968688C185592680 @default.
- W1969968688 hasConceptScore W1969968688C188027245 @default.
- W1969968688 hasConceptScore W1969968688C192562407 @default.
- W1969968688 hasConceptScore W1969968688C21951064 @default.
- W1969968688 hasConceptScore W1969968688C2778439535 @default.
- W1969968688 hasConceptScore W1969968688C521977710 @default.
- W1969968688 hasIssue "4" @default.
- W1969968688 hasLocation W19699686881 @default.
- W1969968688 hasOpenAccess W1969968688 @default.
- W1969968688 hasPrimaryLocation W19699686881 @default.
- W1969968688 hasRelatedWork W1980894458 @default.
- W1969968688 hasRelatedWork W2083053336 @default.
- W1969968688 hasRelatedWork W2089847843 @default.
- W1969968688 hasRelatedWork W2127269464 @default.
- W1969968688 hasRelatedWork W2162280882 @default.
- W1969968688 hasRelatedWork W2329867129 @default.
- W1969968688 hasRelatedWork W2341638127 @default.
- W1969968688 hasRelatedWork W2388113326 @default.
- W1969968688 hasRelatedWork W2899084033 @default.
- W1969968688 hasRelatedWork W2949825340 @default.
- W1969968688 hasVolume "49" @default.
- W1969968688 isParatext "false" @default.
- W1969968688 isRetracted "false" @default.
- W1969968688 magId "1969968688" @default.
- W1969968688 workType "article" @default.