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- W1969971597 abstract "An efficient systematic approach to the diversity-oriented synthesis of polyketides has been developed to provide both skeletal and stereochemical diversity. Each synthetic intermediate is also a desired polyketide fragment and no protecting group manipulations are required. A first-generation synthesis provides a 74-membered polyketide library comprising six different skeletal classes, each in one to five steps from propargylic alcohol precursors. A study of epoxyol opening reactions revealed unusual reactivity trends based on epoxide configuration." @default.
- W1969971597 created "2016-06-24" @default.
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- W1969971597 date "2007-04-17" @default.
- W1969971597 modified "2023-10-15" @default.
- W1969971597 title "A Unified Synthetic Approach to Polyketides Having Both Skeletal and Stereochemical Diversity" @default.
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- W1969971597 doi "https://doi.org/10.1021/ol070405p" @default.
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