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- W1969975771 abstract "A detailed EPR study of a new center appearing in iron-contaminated AgGa${mathrm{S}}_{2}$ crystals after band-to-band photoexitation and having a nearly isotropic $g$ value of 4.3ifmmodepmelsetextpmfi{}0.15 is reported. To interpret the experimental results, by analogy with the iron defects observed in II-VI compounds, we fit the $^{6}S$ manifold of states with a spin Hamiltonian of the form: $H=gensuremath{beta}stackrel{ensuremath{rightarrow}}{mathrm{B}}ifmmodecdotelsetextperiodcenteredfi{}stackrel{ensuremath{rightarrow}}{mathrm{S}}+D[{{S}_{z}}^{2}ensuremath{-}frac{1}{3}S(S+1)]+E({{S}_{x}}^{2}ensuremath{-}{{S}_{y}}^{2})$. Several possible atomic defect configurations are given; among these, one would be the analog of the ${mathrm{Fe}}^{3+}$-$X$ centers observed in II-VI compounds taking into account the cation ordering of the chalcopyrite structure. Although the chemical nature of $X$ could not be identified in the present case, these results seem to corroborate the close analogy among the defects occuring in II-VI and I-III-${mathrm{VI}}_{2}$ compounds." @default.
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- W1969975771 date "1980-03-01" @default.
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- W1969975771 title "Electron paramagnetic resonance of an iron-associated defect in AgGa<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>S</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W1969975771 doi "https://doi.org/10.1103/physrevb.21.1757" @default.
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