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- W1969988966 abstract "A convergent diastereoselective synthesis of racemic aristoserratine ((±)-24) via an intramolecular iminium-ion cyclization is described. The pivotal imine (±)-19 was prepared by condensation of the two building blocks (± )-trans-8-amino-3-(2,6-difluorobenzyloxy)-1-p-menthene ((±)-11) and N-(p-methoxybenzenesulfonyl)-3-indo-leacetaldehyde (18) which were synthesized from (±)-trans-1-p-menthene-3,8-diol ((±)-7) and 3-indoleacetic acid, respectively. On the route to the target (±)-24, two previously unknown indole alkaloids have been characterized, namely (±)-‘anti’-hobartin-15-ol ((±)-22) and (±)-‘anti’-aristotelin-15-ol ((±)-23)." @default.
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- W1969988966 date "1989-03-15" @default.
- W1969988966 modified "2023-09-23" @default.
- W1969988966 title "Synthesis of<i>Aristotelia</i>-Type Alkaloids.. Part IV. Synthesis of (±)-aristoserratine" @default.
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- W1969988966 doi "https://doi.org/10.1002/hlca.19890720209" @default.
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