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- W1970002016 abstract "Abstract The ligands triphenylphosphinoxide, tris(2-diphenylphosphorylmethyl)amine and tris(2-diphenylphosphorylethyl)amine have been found to displace the coordinated water molecules from the [Be(H2O)4]2+ cation, in quite mild conditions, to give respectively the complexes [Be(OPPh3)4](ClO4)2, 1, [(N(CH2PPh2O)3)Be(OH2)](ClO4)2, 2 and [(N(CH2CH2PPh2O)3)Be(OH2)](ClO4)2, 3. The compounds have been characterized through NMR spectroscopy and X-ray crystallography. Complex 2 is the first beryllium complex with a ligand containing the phosphoryl function, whose molecular structure has been determined by an X-ray diffraction study." @default.
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- W1970002016 date "2000-07-01" @default.
- W1970002016 modified "2023-09-25" @default.
- W1970002016 title "Beryllium complexes with mono- and tripodal- phosphinoxide ligands. X-ray crystal structure of [{N(CH2PPh2O)3}Be(OH2)](ClO4)2" @default.
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- W1970002016 doi "https://doi.org/10.1016/s1387-7003(00)00092-7" @default.
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