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• W1970022512 abstract "Several silver(I) complexes with chiral amino-N-heterocyclic carbene (NHC) ligands, which are not diastereomerically pure, were prepared and used to generate in situ chelating NHC–amino palladium(II) complexes. The potential of these palladium(II) complexes in asymmetric catalysis was evaluated in the allylic alkylation reaction. The influence of the structure and of the diastereomeric purity of the ligands on enantioselectivity, as well as the role of the silver salts, were studied. Enantiomeric excesses of up to 80% were obtained with the best ligand." @default.
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• W1970022512 date "2007-02-01" @default.
• W1970022512 modified "2023-10-14" @default.
• W1970022512 title "Palladium catalyzed asymmetric allylic alkylation using chelating N-heterocyclic carbene–amino ligands" @default.
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• W1970022512 doi "https://doi.org/10.1016/j.tetasy.2007.01.019" @default.
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