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- W1970023260 abstract "Abstract The reactivity of both the monoanionic and dianionic forms of bis(diphenylthiophosphinoyl)methane ( 2 – and 2 2– ) as well as the dianion of tetraisopropyl methylenediphosphonate( 3 2– ) was investigated towards the same Co II precursor CoCl 2 . Monoanion 2 – coordination yields a homoleptic zwitterionic Co II complex. However, both dianions ( 2 2– and 3 2– ) give the same overall structure with a square Co 2 C 2 core. Structures of all of the complexes have been confirmed by full NMR spectroscopic analysis and X‐ray diffraction. Furthermore, DFT calculations have been carried out to rationalize the stability of such species." @default.
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- W1970023260 date "2011-04-21" @default.
- W1970023260 modified "2023-10-13" @default.
- W1970023260 title "Coordination Behavior of the S–C–S Monoanion and O–C–O and S–C–S Dianions toward Co <sup>II</sup>" @default.
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- W1970023260 doi "https://doi.org/10.1002/ejic.201100144" @default.
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