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- W1970037717 abstract "Both a face-selective and a non-face-selective mode of formation of quaternary centers of isoprene-derived structural moieties of the natural alkaloid paraherquamide A (1) have been discovered by feeding experiments on Penicillium fellutanum with [U-13C6]-glucose and [13C2]-acetate. The labeling patterns suggest that the methyl groups (C22, C23) are introduced in a non-face-selective manner by a reverse prenyl transferase. The C5 unit comprising the dioxepin moiety retains stereochemical integrity indicative of a single, face-selective addition of the phenolic group to the dimethylallyl group." @default.
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- W1970037717 date "1999-03-15" @default.
- W1970037717 modified "2023-10-11" @default.
- W1970037717 title "Reverse versus Normal Prenyl Transferases in Paraherquamide Biosynthesis Exhibit Distinct Facial Selectivities" @default.
- W1970037717 doi "https://doi.org/10.1002/(sici)1521-3773(19990315)38:6<786::aid-anie786>3.0.co;2-7" @default.
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