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- W1970043852 abstract "Abstract The enantiomers of eight pyrethroid insecticides have been separated by three polysaccharide‐based chiral stationary phases (CSP), namely Chiralcel OD‐R, Chiralpak AD, and Chiralcel OJ, both in reversed and normal phase modes. Deltamethrin, fenpropathrin, and lambda‐cyhalothrin could be baseline separated on Chiralcel OD‐R in reversed phase mode with R s values of 1.39, 1.29, and 1.17, respectively. However, the best separations for deltamethrin and fenpropathrin and tau‐fluvalinate were achieved when the mobile phase was 15% of ethanol in water. Lambda‐cyhalothrin enantiomers were separated using a mobile phase composed of 30% of acetonitrile:water (30:70 v/v). In normal phase mode, Chiralcel OJ gave better chiral separation for those pyrethroids than that of Chiralpak AD. The chiral separation conditions for eight pyrethroid insecticides have been discussed." @default.
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- W1970043852 date "2004-01-01" @default.
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- W1970043852 title "Chiral Separation of Several Pyrethroids on Polysaccharide‐Based Chiral Stationary Phases Under Normal and Reversed Phase Modes" @default.
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- W1970043852 doi "https://doi.org/10.1081/jlc-120034088" @default.
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