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- W1970048630 abstract "The nature of the intermolecular interactions involving the CN groups in organic nitriles has been investigated through comparison of the physical properties of nitriles and other organic liquids. Evidence is presented that hydrogen bonding is not a significant factor in these interactions. The CN groups tend to associate in pairs by dipole interaction, leading to partial dimerization in mononitriles and to longer-range association in dinitriles. The energy of interaction between two CN groups is high, about 8 kcal./mole; it is proposed to call this interaction a CN dipole-pair bond, by analogy with the hydrogen bond. Equations are derived for energies of interaction between dipoles separated by relatively short distances." @default.
- W1970048630 created "2016-06-24" @default.
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- W1970048630 date "1960-01-01" @default.
- W1970048630 modified "2023-10-16" @default.
- W1970048630 title "Intermolecular association in organic nitriles; the CN dipole-pair bond" @default.
- W1970048630 doi "https://doi.org/10.1002/pol.1960.1204213907" @default.
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