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• W1970057786 abstract "A novel porphyrinic receptor 1 in which two zinc porphyrins are bridged by two diarylurea linkers was developed for recognition of a viologen derivative (hexyl viologen, HV). The electronic absorption spectra as well as the 1H NMR experiments revealed that the HV molecule was bound to the cleft in 1 mainly through carbonyl dipole-charge interactions to afford a 1:1 complex. From the steady-state fluorescence spectroscopic study, the photoinduced electron transfer (PET) from 1 to HV was extremely facilitated by the receptor−substrate complexation. The receptor 1 also formed a 1:1 complex with 1,4-diazabicyclo[2.2.2]octane (DABCO) through two Zn−N coordination interactions, and, using DABCO as an inhibitor, we suppressed the PET reaction via the substrate exchange." @default.
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• W1970057786 date "2003-03-18" @default.
• W1970057786 modified "2023-10-17" @default.
• W1970057786 title "Diarylurea-Linked Zinc Porphyrin Dimer as a Dual-Mode Artificial Receptor: Supramolecular Control of Complexation-Facilitated Photoinduced Electron Transfer" @default.
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• W1970057786 doi "https://doi.org/10.1021/ja0294717" @default.
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