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- W1970071004 abstract "The activation of SiO2-supported Pd solids with chiral hydrogen donors such as (R)-(+)- or (S)-(−)-limonene produces catalysts with a special feature, namely, the presence of metal-bound limonene species on the surface. A surface complex between limonene and Pd2+ ions is postulated from TPD/TCD, TPD/MS, XPS, and 13C CP/MAS NMR data. On the basis of the results, the configuration of the stereosite in the hydrogen donor is not altered as the surface-binding interaction does not involve the asymmetric site in limonene." @default.
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- W1970071004 date "1999-08-01" @default.
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- W1970071004 title "Surface Characterization of Supported Pd Catalysts Activated with Chiral Hydrogen Donors" @default.
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- W1970071004 doi "https://doi.org/10.1021/la990053y" @default.
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