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- W1970072553 abstract "Abstract The stereochemistry of the insertion product of acetylenes with platinum hydrides depends on (1) the electron-withdrawing capabilities of the substituents on the acetylene, (2) the nucleophilicities of the solvent and/or anion present, and (3) the reaction temperature. These observations further substantiate our proposed mechanism involving the collapse of a 4-coordinate intermediate, cis -HPt(PEt 3 ) 2 (acetylene) + , to 3-coordinate Pt(PEt 3 ) 2 (vinyl) + ." @default.
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- W1970072553 date "1975-06-01" @default.
- W1970072553 modified "2023-10-18" @default.
- W1970072553 title "Stereochemistry of insertion of disubstituted acetylenes into hydridoplatinum(II) complexes" @default.
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- W1970072553 doi "https://doi.org/10.1016/s0022-328x(00)92101-6" @default.
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